固体热塑性苯基苯酚甲醛树脂的固体酸催化法合成新工艺研究  

Study on a New Composition Technology of Solid Thermoplastic Phenyl Phenol and Formaldehyde Resin by Solid Acid Catalysis

作　　者：王德堂[1] 周立雪[1] 冷士良[1] 吴昊[1] 乔卉莹[1] 

机构地区：[1]徐州工业职业技术学院,江苏徐州221140

出　　处：《化工时刊》2007年第4期19-22,共4页Chemical Industry Times

基　　金：2005年徐州市科技计划项目(X2005208)

摘　　要：介绍了以邻苯基苯酚和甲醛为原料,运用正交实验法,经过固体酸(阳离子交换树脂)催化缩合、过滤、蒸馏等过程,研制出合成苯基苯酚甲醛树脂产品的一种新型工艺路线。产品外观为红棕色粘稠液体,pH值接近7,能够耐水和酸碱,稳定性好,主要用于船舶漆、粘合剂和橡胶制品等领域。A new composition technology of phenyl phenol and formaldehyde resin was studied, using o - phenyl phenol and formaldehyde as material, by orthogonal experiment means, passing through catalysis condensation, filtration, and distillation etc process by solid acid catalyst （cation exchange resin）. This product was vicious reddle liquid, pH was approximate to 7, and was waterproof, acid - resistant alkali proof and steady, mainly applied to marine paint, adhesive and rubber product etc area.

关 键 词：热塑性苯基苯酚甲醛树脂 固体酸 催化缩合 船舶漆 

分 类 号：TQ323.1[化学工程—合成树脂塑料工业]