α-蒎烯合成蒎酮酰胺的研究  

Synthesis of Pinonamide from α-Pinene

作　　者：梁宏艳[1] 赵文浩 陈海燕[1] 林翠梧[1] 

机构地区：[1]广西大学化学化工学院,广西南宁530004 [2]广西化工研究院,广西南宁530001

出　　处：《化工技术与开发》2007年第4期1-3,共3页Technology & Development of Chemical Industry

基　　金：广西科技攻关资助项目(桂科攻0480005);广西大学科学技术研究重点基金资助项目(2003ZD05)

摘　　要：以松节油的主要成分α-蒎烯为原料,氧化开环得蒎酮酸,蒎酮酸经氯化再氨化合成蒎酮酰胺。在蒎酮酰胺的合成中,着重研究了氯化反应的氯化剂、物料配比、反应温度和反应时间等条件。实验结果表明,以PCl3作氯化剂,反应条件温和,操作方便,蒎酮酰胺产率较高。Pinonamide was synthesized from α-pinene which was the principal constituent of turpentine through the reactions of oxidation, chlorination and ammoniation. The factors affected the chlorination reaction were discussed in detail. The experimental results showed that applied phosphorus trichloride as the chlorinating agent, the process conditions were mild and simple, the yield was good.

关 键 词：Α-蒎烯 蒎酮酸 蒎酮酰胺 合成 

分 类 号：O623.626[理学—有机化学] TQ351.471[理学—化学]