微波法合成红色长余辉发光材料Gd_2O_2S∶Eu,Mg,Ti及其发光特性  

Synthesis of the Red Long Afterglow Phosphor Gd_2O_2S∶Eu, Mg, Ti by Microwave Radiation Method and Its Luminescent Properties

作　　者：翟永清[1] 刘元红[1] 孟媛[1] 张少阳[1] 

机构地区：[1]河北大学化学与环境科学学院,河北保定071002

出　　处：《光谱学与光谱分析》2007年第4期634-638,共5页Spectroscopy and Spectral Analysis

基　　金：河北省教育厅博士基金项目(B2004205);河北大学研究基金项目(y2004024)资助

摘　　要：用微波辐射法首次合成了Gd2O2S∶Eu,Mg,Ti红色磷光化合物,用X射线粉末衍射（XRD）、扫描电镜（SEM）、荧光分光光度计等对合成产物进行了分析和表征。结果表明：材料的晶体结构为六方晶系,与Gd2O2S的相同。颗粒的形貌为类球形,分散性较好,尺寸在1-2μm之间。Gd2O2S∶Eu,Mg,Ti的激发光谱呈带状,激发光谱主峰位于360nm,另外在400,422,472nm等处也有激发峰存在;发射光谱为线状光谱,归属于Eu^3＋的5^DJ（J=0,1,2）到7^FJ（J=0,1,2,3,4）的跃迁。随着Eu浓度的增加,位于蓝绿区的586,557,541,513,498,471,468nm处的发射峰逐渐减弱,而主峰位于627nm处的红光发射明显增强。当Eu浓度为6mol%时,红光发射最强。Mg,Ti共掺杂可显著改善其余辉性质。Gd2O2S ： Eu, Mg, Ti, a novel red long afterglow phosphor, was synthesized in microwave field. The synthesized phosphors were investigated respectively by XRD, SEM and fluorescence spectrophotometer. The results show that Gd2O2 S ： Eu, Mg, Ti phosphors possess hexagonal crystal structure, which is similar to that of Gd2O2 S. The particles of Gd2O2 S ： Eu, Mg, Ti phosphors are basically spherical in shape, with good dispersing. The mean particle size is 1：2 μm. The excitation spectrum is a broad band and the main peak is at 360 nm. Moreover, excitation peaks at 400,422 and 472 nm were found in the excitation spectrum. The emission spectrum shows that Gd2O2 S ： Eu, Mg, Ti has narrow emission peaks. The emission peaks are ascribed to Eu^3＋ ions transition from 5^DJ（J= 0, 1, 2） to 7^FJ（J=0, 1, 2, 3, 4）. With the increase in Eu^3＋ molar ratio, the emission peaks at 586, 557, 541, 513,498, 471 and 468 nm in the blue and green region weaken gradually relative to the main emission peak at 627 nm. Therefore the red emitting at 627 nm becomes strong gradually. When the molar ratio is 6 %, the red emitting becomes the strongest. The Ti and Mg co-doping can obviously improve its long-afterglow property.

关 键 词：Gd2O2S Eu Mg Ti 微波法 激发光谱 发射光谱 长余辉 

分 类 号：O614.3[理学—无机化学]