对苯二胺和均苯三酸及对氨基苯甲酸制备可溶性芳香聚酰胺共聚物的研究  

PREPARATION OF SOLUBLE AROMATIC POLYAMIDE COPOLYMERS BY POLYCODENSATION OF p-PHENYLENE DIAMINE,TRIMESIC ACID AND p-AMINDBENZOIC ACID

作　　者：许小聪[1] 刘美华[1] 卢彦兵[1] 徐伟箭[1] 

机构地区：[1]湖南大学化学化工学院,长沙410082

出　　处：《高分子学报》2007年第4期308-313,共6页Acta Polymerica Sinica

基　　金：教育部博士点基金(基金号20030532003)资助项目

摘　　要：分别通过一步加料和分步加料的方法,以对苯二胺(A2)、均苯三酸(B3)和对氨基苯甲酸(AB)为原料进行溶液缩聚反应,制备了具有良好溶解性的芳香聚酰胺共聚物.产物的结构通过IR、1H-NMR得到证实.采用IR和1H-NMR对一步加料共聚反应的共聚行为进行研究,并初步考察了3种不同单体对反应的影响.A series of soluble aromatic polyamide copolymers were prepared by the one-step polymerization or two-step polymerization of p-phenylene diamine （A2 monomer）, trimesic acid （ B3 monomer）, and p-aminobenzoic acid （AB monomer）. The structure of resulting polymers was confirmed by IR, ^1H-, and ^13C-NMR measurements. The copolymerization behavior was investigated by IR and ^1H-NMR. ^1H-NMR spectra of the polymers indicated that the AB monomer reacted by inches with the increasing of reaction time. The copolymers synthesized by two-step polymerization had different structures as compared with the one-step copolymer. The influence of three different monomers on the polymerization was investigated.

关 键 词：溶液缩聚法 共聚酰胺 共聚行为 

分 类 号：O633.22[理学—高分子化学]