Two New Isoprenylated Stilbenes from Artocarpus chama  

Two New Isoprenylated Stilbenes from Artocarpus chama

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作  者:Yong-Hong Wang Ai-Jun Hou Dao-Feng Chen 

机构地区:[1]Department of Pharmacognosy, School of Pharmacy, Fudan University, Shanghai 200032, China

出  处:《Journal of Integrative Plant Biology》2007年第5期605-608,共4页植物学报(英文版)

基  金:Supported by the National Natural Science Foundation of China (30572247) and Shanghai Municipal Education Commission (04YQHB009).

摘  要:Two new stllbenes with two Isoprenoid groups, namely artostllbenes A (compound 1) and B (compound 2), were Isolated from the stems of Arfocarpus chama Buch.-Ham. by repeated column chromatography. The& structures were elucldated as (E)-4-[2-(7-meth-xy-2-2-d-methy-6-(3-methy-but-2-eny-)-2H-1-benz-pyran-5-y-)v-ny-]benzene-1- 2-dlol (compound 1) and (Z)-4-[2-(7-meth-xy-2-2-dimethy--6-(3-methy-but-2-eny-)-2H-1-benz-pyran-5-y-)v-ny-]ben- zene-l,2-dlol (compound 2) by spectroscopic methods, mainly by 1D-, 2D-NMR and MS spectra. Compounds 1 and 2 are two cls- and trans-lsomers and compound 2 is the flrst cis-stllbene isolated from Moraceous plants.Two new stllbenes with two Isoprenoid groups, namely artostllbenes A (compound 1) and B (compound 2), were Isolated from the stems of Arfocarpus chama Buch.-Ham. by repeated column chromatography. The& structures were elucldated as (E)-4-[2-(7-meth-xy-2-2-d-methy-6-(3-methy-but-2-eny-)-2H-1-benz-pyran-5-y-)v-ny-]benzene-1- 2-dlol (compound 1) and (Z)-4-[2-(7-meth-xy-2-2-dimethy--6-(3-methy-but-2-eny-)-2H-1-benz-pyran-5-y-)v-ny-]ben- zene-l,2-dlol (compound 2) by spectroscopic methods, mainly by 1D-, 2D-NMR and MS spectra. Compounds 1 and 2 are two cls- and trans-lsomers and compound 2 is the flrst cis-stllbene isolated from Moraceous plants.

关 键 词:Artocarpus chama artostilbenes A and B isoprenylated stilbene Moraceae. 

分 类 号:Q946.82[生物学—植物学] Q949.737.4

 

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