白术、温郁金、贝母、杭白菊中有机磷农药残留的污染调查  

Investigation of organophosphorous insecticides residue in Chinese crude drugs

作　　者：吴加伦[1] 占绣萍[1] 邹耀华[1] 陈时飞[2] 陆光照 来福根[2] 

机构地区：[1]浙江大学华家池校区农药与环境毒理研究所,浙江杭州310029 [2]浙江省食品药品监督管理局,浙江杭州310029

出　　处：《中国中药杂志》2007年第9期798-800,共3页China Journal of Chinese Materia Medica

基　　金：浙江省科技厅一般科技项目(2004C33054)

摘　　要：目的：调查研究白术、温郁金、贝母、杭白菊中11种有机磷农药残留量的污染情况。方法：样品用二氯甲烷提取,并经活性炭和助滤剂-545混合物柱色谱净化,用气相色谱配FPD进行测定。结果：3档农药的添加平均回收率在77.5%~112.3%,RSD均小于10%（n=4）。在白术、杭白菊等中药材中检测出痕量有机磷农药的残留。结论：本实验选取白术（根）、温郁金（根茎）、贝母（鳞茎）、杭白菊（花）中药材进行有机磷农药的多残留检测,为评价我国中药材中的有机磷农药污染状况提供科学依据。Objective： To study eleven organophosphorus insecticides residuals in four kinds of Chinese crude drugs. Method： The organophosphorus insecticides were extracted with dichloromethane and cleaned-up with a mixture of Celite 545-activated carben. The extracts were analyzed by gas chromatography equipped with a flame photometric detector （FPD）. Result： Analysis of fortified Chinese crude drug showed that the average recoveries ranged from 77. 5%-112. 3% at three different levels, the RSDs were below 10% （n = 4）. Trace organophosphorous pesticide residues were found in samples of Rhizoma Atractylodis Macrocephalae and Flos Chrysanthemi. Conclusion： A method was established for determination muhi-residues in Rhizma Atractylodis Macrocephalae, Radix Curcumae, Bulbus Fritillariae Thunbergii and Flos Chrysanthemi. It provides a method for the risk assessment of organophosphorous pesticide in Chinese crude drugs.

关 键 词：中草药 有机磷农药 多残留分析 

分 类 号：S481.8[农业科学—农药学]