有机物3,4,5,6-四氯-N-羟基邻苯二甲酰亚胺和1,4-二氨基-2,3-二氯蒽醌催化乙苯的分子氧氧化(英文)  

Organocatalytic Aerobic Oxidation of Ethylbenzene Using 3, 4, 5, 6-Tetrachloro-N-hydroxyphthalimide and 1, 4-Diamino-2, 3-dichloro-anthraquinone

作　　者：杨贯羽[1] 林雪松[1] 赵军峰[1] 张巧红[2] 马红[2] 徐杰[2] 

机构地区：[1]郑州大学化学系,河南郑州450052 [2]中国科学院大连化学物理研究所,辽宁大连116023

出　　处：《分子催化》2007年第2期97-98,共2页Journal of Molecular Catalysis(China)

基　　金：The National Science Foundation of China(No. 20473088).

摘　　要：合成了3,4,5,6-四氯-N-羟基邻苯二甲酰亚胺并与1,4-二氨基-2,3-二氯蒽醌组合成有机催化体系.在无溶剂条件下,该体系能够有效催化乙苯的分子氧氧化.Recently, N-hydroxyphthalimide （NHPI） attracted continuous attention due to its high catalytic efficiencies for aerobic oxidation of hydrocarbons, the important industrial processes, in combination with some metallic co-catalysts. We reported firstly an organocatalytic system encompassing anthraquinones and NHPI for efficient selective oxygenation of hydrocarbon . In its catalysis, 1,4-diamino-2,3-dichloro- anthraquinone （DACAQ） was found to be more effective than other used anthraquinones.

关 键 词：有机催化 乙苯 氧化 3 4 5 6-四氯-N-羟基邻苯二甲酰亚胺 1 4-二氨基-2 3-二氯蒽醌 

分 类 号：O643.32[理学—物理化学]