含长链烷基芘类衍生物的合成与氧猝灭特性  

Synthesis and oxygen quenching of pyrene derivatives containing long chain alkyl

作　　者：晏华[1] 王雪梅[1] 余荣升[1] 张斌[1] 陈淑莲[1] 

机构地区：[1]中国人民解放军后勤工程学院军事油料应用与管理工程系,重庆400016

出　　处：《功能材料》2007年第5期795-797,801,共4页Journal of Functional Materials

基　　金：后勤工程学院学术创新基金资助项目(YZ05-43501)

摘　　要：采用酯化反应,合成了系列芘丁酸烷基酯和烷基酸芘丁酯,用IR和1HNMR表征分子结构,采用荧光分光光度计测定了它们在溶液中的荧光特性。结果表明,芘类衍生物的取代基、键桥对激发波长、发射波长和氧猝灭系数的影响较大,以OOC键结方式的烷基酸芘丁酯具有更高的氧猝灭性能,烷基链长短对荧光强度和氧猝灭系数影响不大。A series of 1-alkyl-4-（1-pyrenyl） butanoate and 4-（1-pyrennyl）-butyl alkyl ester were synthesized by the esterification. The structures were characterized by IR and 1^HNMR. The photophysical properties of these pyrene esters were studied in toluene. The emission spectra of them exhibited monomer emission and excimer emission and the emission were effectively quenching by oxygen. The result showed the substituted groups on pyrene, and the bonds between pyrene and long chain alkyl affected the fluorescence quenching, the 4-（1-pyrennyl）-butyl alkyl ester with OOC have higher oxygen quenching performance than 1-alkyl-4-（1-pyrenyl） butanoate with COO,the long of alkyl linked with pyrene have a little effect on the oxygen sensor performance. The type of emission and quenching sensity were affected gy the concentration of pyrene derivati.

关 键 词：芘衍生物 氧猝灭 荧光分子 压敏涂料 

分 类 号：TP212[自动化与计算机技术—检测技术与自动化装置] TB381[自动化与计算机技术—控制科学与工程]