马来海松酸酐合成新方法的研究  

New method for the synthesis of maleopimaric acid anhydride

作　　者：孟凡君[1] 张俊华[2] 王明刚[2] 孙爱娟[2] 黄明湖[2] 

机构地区：[1]山东大学威海分校海洋学院,山东威海264209 [2]山东大学化学与化工学院,山东济南250100

出　　处：《山东大学学报（理学版）》2007年第3期55-59,共5页Journal of Shandong University(Natural Science)

基　　金：山东省优秀中青年基金资助项目(2004BS04015);山东大学威海分校引进人才科研基金资助项目

摘　　要：通过与环己胺成盐的方法分离松香中的树脂酸,在催化剂对甲基苯磺酸存在下与马来酸酐进行Diels-Alder反应合成马来海松酸酐.当松香、马来酸酐摩尔比为1.9∶1.0,反应温度180℃,反应时间4 h时,MPA的收率可达70.3%.Resin acid was separated from rosin through salt formation with cyclohexylamine. In the presence of p-toluene sulfonic acid as a catalyst, resin acid reacted with maleic anhydride by Diels-Alder reaction. The final product of this reaction is maleopimaric acid anhydride. This reaction was carried out under the circumstances that the molar ratio of rosin to maleic anhydride is 1.9： 1.0, reaction temperature is 180 ℃, and reaction time is 4 h. The synthetic efficiency of maleopimaric acid anhydride is 70.3%.

关 键 词：马来海松酸酐 松香 马来酸酐 DIELS-ALDER反应 

分 类 号：TQ630.4[化学工程—精细化工]