鲁米诺偶联酞菁的合成及其光谱性质的研究  

Study on Synthesis and Spectral Properties of Phthalocyanine Conjugating Luminols

作　　者：黄新[1] 李忠玉[1] 宾月景[1] 黄蕾[1] 张复实[1] 

机构地区：[1]清华大学化学系有机光电子与分子工程教育部重点实验室,北京100084

出　　处：《感光科学与光化学》2007年第3期209-213,共5页Photographic Science and Photochemistry

基　　金：国家自然科学基金项目(20333080;20572059;20502013);国家基础研究项目(2007CB808000)

摘　　要：本文通过重氮化反应设计、合成了鲁米诺偶联的氨基锌酞菁,对其电子吸收光谱和荧光光谱性质进行了研究,结果表明该分子激发单重态可能以振动驰豫的方式使大部分能量耗散,鲁米诺偶联前后,氨基取代锌酞菁的荧光光谱有明显差别,为进一步开发酞菁类荧光光存储材料提供了理论依据.α-Tetra-amino-phthalocyanine zinc（ Ⅱ ） conjugating luminols was designed and synthesized by diazotization method. The electronic absorption spectra and fluorescence spectra of the compound in DMF have been measured and studied. The phenomena of intramolecular electron transfer are found and the fluorescence of phthalocyanine was quenched significantly by luminol moiety. These results showed potential applications in fluorescence data storage.

关 键 词：鲁米诺 氨基取代锌酞菁 电子转移 荧光存储 

分 类 号：O621.2[理学—有机化学]