催化酯化合成丁酸正丁酯的研究进展  

Research Progress on Synthesis of n-butyl Butyrate by Catalytic Esterification

作　　者：刘美艳[1] 俞善信[1] 管仕斌[1] 

机构地区：[1]湖南师范大学化学化工学院,湖南长沙410081

出　　处：《化工文摘》2007年第3期46-49,53,共5页

摘　　要：固体酸催化剂是能够代替硫酸作为酯化的催化剂。文章评述了对甲苯磺酸、甲烷磺酸盐、氨基磺酸、强酸性阳离子交换树脂、三氯化铁、二氯化锡、四氯化锡、硫酸铁铵、硫酸亚铁,硫酸铈、硫酸钛、硫酸氢钠、季铵盐、固体超强酸、杂多酸、分子筛等固体催化剂和酶催化酯化合成丁酸正丁酯的实验结果。Solid acid catalyst can be substituted for sulphuric acid as esterification catalyst. The catalytic Synthesis of n-butyl butyrate with solid catalyst such as p-toluene sulfonic acid, methane sulfonate, amino sulfonic acid, strongly acidic cationic exchange resin, ferric chloride, stannous chloride, stannic chloride, ammonium ferric sulfate, ferrous sulfate, cerium sulfate, titanium sulfate, sodium bisulfate, quaternary ammonium salt, solid supper acid, heteropoly acid, molecular sieve etc and enzyme catalytic esterification was reviewed.

关 键 词：丁酸正丁酯 合成 固体催化剂 催化酯化 

分 类 号：O623.624[理学—有机化学] TQ225.24[理学—化学]