用CTAB/正己醇/水/盐反胶团体系制备纳米ZrO_2超细粉  

SYNTHESIS OF DOPED ZrO 2 NANOPARTICLES BY USING CTAB/HEXANOL/WATER/SALTS REVERSED MICELLES

作　　者：方小龙[1] 杨传芳[1] 陈家镛[1] 

机构地区：[1]中国科学院化工冶金研究所

出　　处：《化工冶金》1997年第1期67-71,共5页

基　　金：国家自然科学基金资助项目

摘　　要：利用ＣＴＡＢ／正己醇／水／盐反胶团体系，制备了含Ｙ２Ｏ３３％（摩尔百分比）的ＺｒＯ２超细粉末，运用冷冻蚀刻复形技术研究了反胶团的微观结构，用ＴＧ－ＤＴＡ、ＸＲＤ、ＴＥＭ、ＳＡＥＤ等分析手段对粉末及其前驱物进行了表征．实验结果表明，ＣＴＡＢ／正己醇／水／盐反胶团体系具有较大的溶盐量，其胶束微观结构良好．所获得的粉末为球形、粒度分布均匀、无硬团聚、粒径约３０ｎｍ的四方相二氧化锆．In this work, nanosize ZrO 2 particles containing 3% Y 2O 3 were prepared by using CTAB/Hexanol/Water/Salts reversed micellar system. The microstructure of these reversed micelles were examined by Freezing-etching TEM technique, the particles were characterized by TG-DTA, XRD, TEM and SAED. Experimental results indicated that the CTAB/Hexanol/Water/Salts reversed micelles have perfect microstructure and sufficient salt uptake. The doped ZrO 2 particles prepared are spherical in shape with narrow size distribution and less agglomeration. The mean size is found to be around 30 nm.

关 键 词：二氧化锆 反胶团 制备 

分 类 号：TF123.72[冶金工程—粉末冶金]