胶溶法制备改性氧化铝的结构及织构特点  

Characteristics of Structure and Texture of Modified Alumina Prepared by Peptizing Method

作　　者：张丽娟[1] 董文萍[1] 陈耀强[1] 史忠华[1] 刘志敏[1] 赵明[1] 龚茂初[1] 

机构地区：[1]四川大学化学学院,成都610064

出　　处：《高等学校化学学报》2007年第5期968-970,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金重点基金(批准号:20333030)资助.

摘　　要：Alumina prepared by peptizing method with a high specific surface area, moderate pore structure and pore size distribution was studied. Furthermore, the effects of additives La and PEG on thermal stability, particle size, structure and texture of alumina were investigated. The results of characterization of BET and XRD show that the addition of La greatly inhibits the loss of specific surface area and α phase transformation of alumina under the hydrothermal and high temperature conditions. At the same time, PEG as an additive can apparently increase pore volume and pore diameter of alumina. The more the La and PEG content is, the larger the surface area, pore volume and average diameter of alumina are. However, when the quantity ratio of La2O3 to Al2O3 or PEG to Al2O3 is excessive, the negative action of La and PEG are stronger. When the quantity ratio of La2O3/Al2O3 is 2.5%—3.0%, thermal stability of γ-Al2O3 is the best and specific surface area of alumina is more than 140 m2/g after hydro thermally being aged at 1000 ℃ for 5 h. Though PEG plays a good role on making pore and aggregation when the value of quantity ratio of PEG/Al2O3 is 80%, the thermal stability of alumina is worse and specific surface area is only 136.4 m2/g, pore volume is 0.41 mL/g and pore diameter is 9.38 nm under the same aging condition. Fortunately, after hydro thermally being aged at 1000 ℃ for 5 h, the alumina containing 2.5%La2O3 and 80%PEG of quantity of alumina has the best thermal stabilization and the largest specific surface area, pore volume and pore diameter that are 156.2 m2/g, 0.57 mL/g and 11 nm, respectively.Alumina prepared by peptizing method with a high specific surface area, moderate pore structure and pore size distribution was studied. Furthermore, the effects of additives La and PEG on thermal stability, particle size, structure and texture of alumina were investigated. The results of characterization of BET and XRD show that the addition of La greatly, inhibits the loss of specific surface area and α phase transformation of alumina under the hydrothermal and high temperature conditions. At the same time, PEG as an additive can apparently increase pore volume and pore diameter of alumina. The more the La and PEG content is, the larger the surface area, pore volume and average diameter of alumina are. However, when the quantity ratio of La2O3 to Al2O3 or PEG to Al2O3 is excessive, the negative action of La and PEG are stronger. When the quantity ratio of La2O3/Al2O3 is 2.5%-3.0% , thermal stability of γ-Al2O3 is the best and specific surface area of alumina is more than 140 m^2/g after hydro thermally being aged at 1000 ℃ for 5 h. Though PEG plays a good role on making pore and aggregation when the value of quantity ratio of PEG/Al2O3 is 80%, the thermal stability of alumina is worse and specific surface area is only 136.4 m^2/g, pore volume is 0. 41 mL/g and pore diameter is 9.38 nm under the same aging condition. Fortunately, after hydro thermally being aged at 1000 ℃ for 5 h, the alumina containing 2. 5% La2O3 and 80% PEG of quantity of alumina has the best thermal stabilization and the largest specific surface area, pore volume and pore diameter that are 156.2 m^2/g, 0. 57 mL/g and 11 nm, respectively.

关 键 词：氧化铝 载体 胶溶 结构 织构 

分 类 号：O648[理学—物理化学]