A Zn(II) 5-Aminoisophthalate Coordination Polymer  

作　　者：TANG En DAI Yu-Mei LI Zhao-Ji WANG Xiao-Qin YIN Pei-Xiu YAO Yuan-Gen 

机构地区：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on theStructure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China [2]College of Chemistry ＆ Material Science, FujianNormal University, Fuzhou, Fujian 350007, China

出　　处：《Chinese Journal of Structural Chemistry》2007年第5期529-532,共4页结构化学（英文）

基　　金：Supported by the National Natural Science Foundation of China (No. 29733090 and 20173063);the State Key Basic Research and Development Plan of China (001CB108906);Key Project in KIP of CAS (KJCX2-H3);the NSF of Fujian Province (E0020001)

摘　　要：The title compound, [Zn（AIP）（4,4-bipy）0.5（H2O）]n·0.75nH2O 1, was synthesized via the hydrothermal reaction of Zn（OAc）2 with 5-aminoisophthalic acid （H2AIP） and characterized by elemental analysis and infrared spectra. The complex crystallizes in monoclinic system, space group P21/c with a = 12.672（1）, b = 7.6557（4）, c = 16.181（1）A, β = 109.187（2）°, V = 1482.6（2）A^3, Z = 1, C52H52N8O23Zn4, Mr = 1418.58, Dc = 1.589 g/cm^3, F（000） = 724 and μ（MoKα） = 1.685mm-1. The final R = 0.0702 and wR = 0.1524 for 1847 observed reflections with Ⅰ〉 2σ（Ⅰ）, and R = 0.0873 and wR = 0.1664 for all data. X-ray diffraction studies reveal that the title compound has an interesting 2D microporous architecture with guest water molecules inside the channel.The title compound, [Zn（AIP）（4,4-bipy）0.5（H2O）]n·0.75nH2O 1, was synthesized via the hydrothermal reaction of Zn（OAc）2 with 5-aminoisophthalic acid （H2AIP） and characterized by elemental analysis and infrared spectra. The complex crystallizes in monoclinic system, space group P21/c with a = 12.672（1）, b = 7.6557（4）, c = 16.181（1）A, β = 109.187（2）°, V = 1482.6（2）A^3, Z = 1, C52H52N8O23Zn4, Mr = 1418.58, Dc = 1.589 g/cm^3, F（000） = 724 and μ（MoKα） = 1.685mm-1. The final R = 0.0702 and wR = 0.1524 for 1847 observed reflections with Ⅰ〉 2σ（Ⅰ）, and R = 0.0873 and wR = 0.1664 for all data. X-ray diffraction studies reveal that the title compound has an interesting 2D microporous architecture with guest water molecules inside the channel.

关 键 词：hydrothermal reaction crystal structure Zn（Ⅱ） complex 5-aminoisophthalic acid 

分 类 号：O614.241[理学—无机化学] O641.4[理学—化学]