AlCl_3催化下C_(60)与脱氢枞胺的胺加成反应  

Amine Addition Reaction of C_(60) with Dehydroabietylamine Catalyzed by AlCl_3

作　　者：高健[1] 林中祥[1] 邓慧敏[2] 

机构地区：[1]南京林业大学化学工程学院,江苏南京210037 [2]中山大学分析测试中心,广东广州510275

出　　处：《南京林业大学学报（自然科学版）》2007年第3期95-98,共4页Journal of Nanjing Forestry University：Natural Sciences Edition

基　　金：国家自然科学基金资助项目(30371139);广东省自然科学基金项目(04009752);南京林业大学人才基金资助项目

摘　　要：研究了脱氢枞胺分子中的芳环结构与C60Friedel-Crafts反应产物。将C60、脱氢枞胺及无水AlCl3在氯苯溶剂中,在避光条件下于130℃反应3 d,反应产物经过柱层析分离,用IR1、H NMR1、3C NMR、ESI-MS等分析方法对反应主要产物进行结构测定,发现并未生成预期的Friedel-Crafts反应产物,却得到C60与脱氢枞胺的胺加成反应产物,主产物为氨基与碳球相连的单加成结构。In order to obtain Friedel-Crafts adduct of C60 with dehydroabietylamine, the reaction of C60 with dehydroabietylamine was carried out in the presence of AlCl3 in chlorobenzene at 130℃ for 3 d in the dark. The derivatives of C60were isolated by silica column chromatographY and characterized by FT - IR,^13 C NMR,^1H NMR, ESI - MS. The results showed that amine addition reaction between C60 and dehydroabietylamine took place instead of Friedel-Crafts reaction, and a mono-adduct of C60 and dehydroabietylamine obtained as the main product. A new synthesis method of C60 and amino was provided.

关 键 词：C40 脱氢枞胺 胺加成 

分 类 号：TQ351[化学工程]