几种新型含氟含氰拟除虫菊酯的合成研究初报  

Preliminary study of synthesis of some kinds of pyrethroids containing fluorine and cyanogen

作　　者：章小波[1,2,3,4,5] 汤淼荣[1,2,3,4,5] 朱畅蟾 章小亚 

机构地区：[1]浙江医科大学医化教研室 [2]杭州大学中心实验室 [3]华东师范大学化学系 [4]椒江市公安局 [5]浙江省椒江市

出　　处：《浙江农业大学学报》1997年第3期282-284,共3页

摘　　要：反－２，２－二甲基－３－（１－甲基－２，２－二氟乙烯基）环丙烷羧酸分别与２－甲基－２－戊烯醛，３－甲基－２－丁烯醛以及３－苯氧基苯甲醛反应，合成了三种新型的含氟含氰拟除虫菊酯．酯化产率为５２～６０％。Three kinds of new pyrethroids fluorine and cyanogen containing have been synthesized by the reactions of trans 2,2 dimethyl 3 (1 methyl 2,2 difluoroving) cyclopropane carboxylic acid with 2 methyl 2 pentenaldehyde, 3 methyl 2 butenaldehyde and 3 phenoxyphenyl aldehyde respectively.The esterification yields were about 52%～60%。The chemical structures of these pyrethroids were confirmed by IR spectra and 1HNMR spectra.

关 键 词：菊醇 菊酸 酯化 拟除虫菊酯 

分 类 号：TQ453.292[化学工程—农药化工]