纳米多孔配位聚合物的研究进展  

Recent developments in nanoporous coordination polymers

作　　者：朱敦如[1] 周俊[1] 杨捷[1] 包魏魏[1] 沈旋[1] 

机构地区：[1]南京工业大学化学化工学院,江苏南京210009

出　　处：《南京工业大学学报（自然科学版）》2007年第3期103-110,共8页Journal of Nanjing Tech University(Natural Science Edition)

基　　金：江苏省高校自然科学研究计划(05KJB150045)

摘　　要：纳米多孔材料可用作催化剂、气体储存材料和光电子器件,是目前新型多孔材料的研究热点之一.借助自组装技术,选择羧酸类、联吡啶类和吡啶羧酸类化合物作为桥联配体,可获得一维、二维和三维的多孔配位聚合物.简要综述了该类纳米多孔配位聚合物的设计原理、合成路线和应用前景,评价了其合成方法的优缺点.由于其特殊的结构和性质,纳米多孔配位聚合物将发展成为具有光、电、磁等性质的多功能材料.Nanoporous materials can be used for catalysis, gas storage, and optoelectronic devices, which is one of extensively researched fields in novel porous materials. One-dimensional （ 1 D）, two-dimensional （2D） and threedimensional （3D） porous coordination polymers can be synthesized by the self-assembly of metal ions and the bridge-linking ligands like carboxylates,bipyridyl compounds and isonictinic acids. The principles of design, synthesis routes and potential applications of the nanoporous coordination polymers have been briefly described, and the advantages and disadvantages of the synthesis methods have been evaluated. Due to their special structures and properties, nanoporous coordination polymers will be developed into multifunctional materials with optical, electronic and magnetic properties.

关 键 词：配位聚合物 多孔材料 结构 纳米材料 

分 类 号：O611.6[理学—无机化学]