Synthesis and Structure of a Novel Rare Earth Complex: Eu_3(dpa dioxide)_4·(CF_3COO)_5·H_2O  

作　　者：刘荫秋 曾锡瑞 刘建强 李多福 温和瑞 

机构地区：[1]College of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University [2]Chemistry Department of Gannan Normal College, Ganzhou, Jiangxi 341000, China [3]Chemistry Department of Gannan Normal College

出　　处：《Chinese Journal of Structural Chemistry》2007年第6期683-686,共4页结构化学（英文）

基　　金：This work was supported by the Natural Science Foundation of Jiangxi Province (No. 0320026 and 0520036)

摘　　要：The novel europium complex Eu3（dpa dioxide）4·（CF3COO）5·H2O （dpa dioxide = di-2-pyridylamine N,N＇-dioxide） was prepared by the reaction of Eu（CF3CO2）3 with Dpa dioxide in acetonitrile under 95 ℃ and determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic system, space group C2/c with a = 41.632（8）, b = 14.662（3）, c = 23.300（4）A,β= 100.862（5）°, Z = 8, D = 1.775 g/cm^3, V = 13968（4）A^3, F（000） = 7232, the final R = 0.0464 and wR = 0.1168. In this tri-nuclear complex, each europium（Ⅲ） is nine-coordinated to adopt an unequal sphere geometry.The novel europium complex Eu3（dpa dioxide）4·（CF3COO）5·H2O （dpa dioxide = di-2-pyridylamine N,N＇-dioxide） was prepared by the reaction of Eu（CF3CO2）3 with Dpa dioxide in acetonitrile under 95 ℃ and determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic system, space group C2/c with a = 41.632（8）, b = 14.662（3）, c = 23.300（4）A,β= 100.862（5）°, Z = 8, D = 1.775 g/cm^3, V = 13968（4）A^3, F（000） = 7232, the final R = 0.0464 and wR = 0.1168. In this tri-nuclear complex, each europium（Ⅲ） is nine-coordinated to adopt an unequal sphere geometry.

关 键 词：SYNTHESIS rear earth complex X-ray single-crystal diffraction LUMINESCENCE 

分 类 号：O627.3[理学—有机化学]