高盐高COD农药废水的处理工程与调试研究  

Studied on the debugging and project of pesticide wastewater with high concentration COD and salt

作　　者：张选军[1] 张亚雷[1] 周雪飞[1] 马秀娟[1] 赵建夫[1] 

机构地区：[1]同济大学环境科学与工程学院,上海200092

出　　处：《工业水处理》2007年第6期22-24,共3页Industrial Water Treatment

摘　　要：某化工厂在生产农药燕麦灵中间体时,排放出含盐质量浓度高达20 g/L、CODCr为14～16 g/L的有毒废水。采用三相蒸馏+水解酸化+缺氧+接触氧化组合工艺处理该废水的工程经过5个月的调试,出水达到工业园区排放标准。通过水解酸化后,废水的CODCr/BOD5从0.12上升到0.32。工程调试过程中缺氧+接触氧化段极为关键,通过小幅度逐步的提高进水盐浓度,有效地驯化了微生物,使之适应了高浓度盐环境并提高了其活性,CODCr的去除率从23%上升到70%。A pesticide plant discharging poisonous wastewater with 20 g/L of salinity and 14-16 g/L CODc, when the intermediate of barban pesticide is produced. With the combining process of three phase distillation ＋ hydrolysis acidification ＋ anoxia ＋ contact oxidation, the effluent water quality conforms to the discharge standard of industrial areas after five-month debugging. The ratio of CODc, to BOD5 moves up to 0.32 from 0.12 when the wastewater has been hydrolyzed and acidificated. The anoxia ＋ contact oxidation process is the key step during the whole project debugging. The microorganisms have been domesticated alive through increasing the salinity step by step and the removal rate has been increased to 70% from 23% under the higher salinity circumstance of contact oxidation.

关 键 词：含盐废水 农药废水 接触氧化 水解酸化 

分 类 号：X703.1[环境科学与工程—环境工程]