线型聚苯乙烯支载噁唑烷酮手性助剂的合成研究  

Studies on synthesis of NCPS supported oxazolidinone chiral auxiliary

作　　者：卢翠芬[1] 卢黎明[1] 陈祖兴[1] 杨桂春[1] 

机构地区：[1]湖北大学化学化工学院,湖北武汉430062

出　　处：《湖北大学学报（自然科学版）》2007年第2期167-169,共3页Journal of Hubei University：Natural Science

基　　金：国家自然科学基金(No:20372019)资助课题

摘　　要：从手性噁唑烷酮出发,经两步反应得到可溶性线型聚苯乙烯支载的噁唑烷酮手性助剂,总产率为48.5%.通过IR,1H NMR,13C NMR,GPC,TG和元素分析对聚合物进行表征,发现得到的线型聚苯乙烯支载的噁唑烷酮手性助剂具有很好的溶解性,较低的分子量(Mw=7 000),较高的支载量(Loading=2.41mmol/g)和很好的热稳定性(Td5%=337.5℃),是一个优良的手性辅助试剂.NCPS supported oxazolidinone chiral auxiliary was synthesized using oxazolidinone as initiating chiral material by two steps and total yield of the reactions was 48. 5G. The obtained polymers were characterized by IR, ^1H NMR,^13C NMR, GPC, TG and elementary analysis. We found NCPS supported oxazolidinone chiral auxiliary had good solubility, lower molecular weight（Mw = 7 000）, high support capability（Loading = 2. 41 mmol/g）, and good thermal stability（Ta^5% = 337.5 ℃）, it was a good chiral auxiliary.

关 键 词：线型聚苯乙烯 支载 噁唑烷酮 手性助剂 合成 

分 类 号：O621.34[理学—有机化学]