吡唑及吡嗪类含能化合物研究进展  

Advance in Energetic Compounds Derived from Pyrazole and Pyrazine

作　　者：雷永鹏[1] 徐松林[1] 阳世清[1] 张彤[1] 

机构地区：[1]国防科技大学航天与材料工程学院,湖南长沙410073

出　　处：《化学研究》2007年第2期107-112,共6页Chemical Research

基　　金：国家自然科学基金委员会-中国工程物理研究院"NSAF"联合基金资助(10376042)

摘　　要：吡唑和吡嗪分别为分子中含两个氮原子的五元和六元杂环,是富氮杂环化合物的理想结构单元.部分具有生成焓高、热稳定性好和感度较低等特点.介绍了吡唑、吡嗪类高氮杂环含能化合物的合成、性能以及在含能材料中的应用研究进展,其中LLM-105和ANPZ-i在钝感炸药中应用前景良好,预测了两类含能化合物的发展前景.Pyrazole and pyrazine are five and six heterocyclic compounds containing two nitrogen atoms respectively. As high-nitrogen heterocylic compounds, they have ideal constructure. Some of them have high formation enthalpy, fine thermal stability and good safety characteristics. The research and development status of high nitrogen heterocylic energetic compounds derived from pyrazole and pyrazine is reviewed. LLM-105 and ANPZ-i are attractive for applications in insensitive munitions due to its high energy level, moderate sensitivity, and good thermal stability. The future development of these two types of energetic compounds is proposed.

关 键 词：含能材料 吡唑 吡嗪 炸药 综述 

分 类 号：TQ56[化学工程—炸药化工] O621[理学—有机化学]