1,1-双环戊二烯基-2,3-二苯基-7-甲基-1-锆杂茚的合成与反应  

Synthesis and Reactions of 1, 1-Di-cyclopentadienyl-2,3-diphenyl-7-methyl- 1-zirconoindene

作　　者：陈美文[1] 宁克远 

机构地区：[1]南开大学化学系

出　　处：《高等学校化学学报》1990年第7期754-755,共2页Chemical Journal of Chinese Universities

摘　　要：利用热分解反应可以合成钛杂茚类衍生物。我们曾试图通过Cp₂ZrPh₂与PhC≡CPh的热分解反应合成锆杂茚,但末成功。后来发现具有邻位取代基的Cp₂Zr（o-甲苯基）能与PhC≡CPh生成高产率的锆杂茚络合物:By the thermolysis of di-o-tolylzirconocene and tolane, new zirconoindene complex was obtained with a high yield. The data of elemental analysis, spectra and MS were provided. The acidoly-sis and iodolysis of zirconoindene were studied, By the identifications of the products, the structure of zirconoindene was determined. Because of the high yield and selectivity in the formation and acidolysis of zirconoindene, these reactions are useful in stereo-specific organic syntheses.

关 键 词：锆杂茚 热分解 金属环 

分 类 号：O627.43[理学—有机化学]