聚甲基丙烯酸烷基磺酸盐-聚双吡啶分子复合物研究  

STUDIES ON THE INTERMACROMOLECULE COMPLEX COMPOSED OF POLY (SULFOALKYL METHACRYLATE) AND POLYVIOLOGEN

作　　者：万国祥[1] 王兵[1] 刘三超[2] 张京 

机构地区：[1]中国科学院成都有机化学研究所 [2]成都科技大学

出　　处：《高分子材料科学与工程》1990年第4期83-87,共5页Polymer Materials Science & Engineering

基　　金：国家自然科学基金

摘　　要：高分子烷基磺酸盐与聚双吡啶在溶液中形成的大分子复合物具有很好的电化学稳定性。在三元溶剂中的最大溶解度为1.58g/ml;在—0.0v和—0.6v电压下分别显示无色和蓝紫色,响应时间为100ms。In order to improve the electrostability, response speed, and solubility of polyviologen complexes, the intermacromolecule complex (PSHMA-m - PXV) based on poly (sulfoalkyl methacrylate) and polyviologen was synthesized. Cyclic Voltammogram shows that the complex film coated on a graphite electrode has a good electrochemical stability.Potential-step test gives a response speed of about 100ms. The phase diagrams of complex in the mixed solution composed of H2O, DMF, and salt (NaCl or NaBr) were also investigated.

关 键 词：聚双吡啶 烷基磺酸盐 大分子复合物 

分 类 号：O633.2[理学—高分子化学]