Template growth mechanism of spherical Ni(OH)_2  被引量:3

Template growth mechanism of spherical Ni(OH)_2

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作  者:彭美勋 沈湘黔 

机构地区:[1]School of Geoscience and Environmental Engineering Central South University [2]Changsha Research Institute of Mineral and Metallurgy, Changsha 410012, China [3]Changsha Research Institute of Mineral and Metallurgy [4]College of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China

出  处:《Journal of Central South University of Technology》2007年第3期310-314,共5页中南工业大学学报(英文版)

基  金:Project(50134020) supported by the National Natural Science Foundation of China;Project supported by Postdoctoral Fund of Central South University

摘  要:The microstructures and growth process characteristics precipitation-crystallization method were investigated by SEM, TEM of spherical Ni(OH)2 particles synthesized by the aqueous and XRD, and their growth mechanism was discussed. With the reaction beginning and continuing, amorphous Ni(OH)2 nano-crystallites grow up to spherical micron-particles with radially arranged crystallites. The nucleation, crystallization and re-crystallization led by Ostwald ripening simultaneously take place through the whole growth processes. With the course from reversible aggregation to irreversible agglomeration, the Ni(OH)2 particles tend to grow according to the template growth model: the growth on the crystallite templates stretching in the radius directions is free and quick, while the growth rate for crystallites in other directions is confined due to lower monomers concentration and tends to dissolve So it is only the radially arranged crystallites that predominate in the particle and lead to characteristic microstructures.The microstructures and growth process characteristics of spherical Ni(OH)2 particles synthesized by the aqueous precipitation-crystallization method were investigated by SEM, TEM and XRD, and their growth mechanism was discussed. With the reaction beginning and continuing, amorphous Ni(OH)2 nano-crystallites grow up to spherical micron-particles with radially arranged crystallites. The nucleation, crystallization and re-crystallization led by Ostwald ripening simultaneously take place through the whole growth processes. With the course from reversible aggregation to irreversible agglomeration, the Ni(OH)2 particles tend to grow according to the template growth model: the growth on the crystallite templates stretching in the radius directions is free and quick, while the growth rate for crystallites in other directions is confined due to lower monomers concentration and tends to dissolve. So it is only the radially arranged crystallites that predominate in the particle and lead to characteristic microstructures.

关 键 词:spherical Ni(OH)2: microstructure Ostwald ripening growth mechanism CRYSTALLIZATION 

分 类 号:O614.813[理学—无机化学]

 

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