Experimental investigation of incremental reactivity of di-tert-butyl peroxide  

作　　者：DU Lin XU YongFu GE MaoFa JIA Long YAO Li 

机构地区：[1]Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China [2]State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China [3]Graduate University of the Chinese Academy of Sciences, Beijing 100039, China [4]Research Center for Atmospheric Environment, Beijing Normal University, Beijing 100875, China

出　　处：《Chinese Science Bulletin》2007年第12期1629-1634,共6页

基　　金：Supported by the Knowledge Innovation Program of the Chinese Academy of Sci-ences as part of "A Preliminary Study of the Formation and Evolution Mechanism of Photochemical Smog in the Beijing Region and Its Control Experiments" (Grant No. KJCX2-SW-H8);Hundred Talents Fund and the National Natural Science Founda-tion of China (Grant Nos. 20577052, 20673123, 20473094 and 20503035)

摘　　要：Large quantities of di-tert-butyl peroxide (DTBP) have been emitted into the troposphere due to human activities. Its role in the atmospheric photochemical reaction has not been understood. This study presents the results of the photochemical reactions of DTBP and NOx, which have been simulated in a self-made smog chamber under the temperature of (29±1)℃. Both the wall decays of ozone and NO2 could be neglected, compared to the results in simulative experiments. The effective intensity of UV light used in the experiments was 1.28×10-3 s-1, which was expressed by the rate constant of NO2 photolysis in purified air. The reaction mechanism was proposed according to our results and reports of other researchers. The maximum values of incremental reactivity (IR) in the three simulative ex- periments were 9.53×10-2, 5.23×10-2 and 3.78×10-2, respectively. The incremental reactivity decreased with the increase of initial concentrations of DTBP. The IR value of DTBP obtained in this study was comparable to that of acetylene reported in our previous research.Large quantities of di-tert-butyl peroxide （DTBP） have been emitted into the troposphere due to human activities. Its role in the atmospheric photochemical reaction has not been understood. This study presents the results of the photochemical reactions of DTBP and NO,, which have been simulated in a self-made smog chamber under the temperature of （29±1）℃. Both the wall decays of ozone and NO= could be neglected, compared to the results in simulative experiments. The effective intensity of UV light used in the experiments was 1.28×10^-3 s^-1, which was expressed by the rate constant of NO2 photolysis in purified air. The reaction mechanism was proposed according to our results and reports of other researchers. The maximum values of incremental reactivity （IR） in the three simulative experiments were 9.53^10^-2, 5.23×10^-2 and 3.78×10^-2, respectively. The incremental reactivity decreased with the increase of initial concentrations of DTBP. The IR value of DTBP obtained in this study was comparable to that of acetylene reported in our previous research.

关 键 词：双特丁基过氧化物 烟雾室 光化反应 光化烟雾 大气化学 

分 类 号：P402[天文地球—大气物理学与大气环境]