A new radical way to N,N-dimethylaniline hydroperoxide (DMAHP) and its application in organic synthesis  

作　　者：Yi Xu Shi Lei Zhang Wen Hu Duan 

机构地区：[1]Shanghai Institute of Materia Medica, Shanghai Institutes of Biological Sciences, Chinese Academy of Sciences,Graduate School of the Chinese Academy of Sciences, Shanghai 201203, China

出　　处：《Chinese Chemical Letters》2007年第7期807-810,共4页中国化学快报（英文版）

摘　　要：N,N-Dimethylaniline hydroperoxide was obtained when treating N,N-dimethylaniline with NHPI/Co（OAc）2/O2 via a radical reaction mechanism. This intermediate has potential application in the synthesis of some important chemical scaffolds.N,N-Dimethylaniline hydroperoxide was obtained when treating N,N-dimethylaniline with NHPI/Co（OAc）2/O2 via a radical reaction mechanism. This intermediate has potential application in the synthesis of some important chemical scaffolds.

关 键 词：Aerobic oxidation NHPI N N-Dimethylaniline 

分 类 号：O625.6[理学—有机化学]