功能大分子金属轮烷和索烃的研究进展  

Progress in Study of Functional Supermolecular Metal-complexed Rotaxanes and Catenanes

作　　者：隋锡娜[1] 鲁晓明[1] 

机构地区：[1]首都师范大学化学系,北京100037

出　　处：《化学通报》2007年第7期494-500,共7页Chemistry

基　　金：北京市自然科学基金资助项目(2012005)

摘　　要：金属轮烷和金属索烃是通过在轮烷和索烃中引入金属离子或金属配合物而制得的,它们不仅结构特殊,而且具有许多特殊的性质,因此受到化学家们的广泛关注。本文综述了近几年来金属轮烷和金属索烃在分子机器、分子开关、仿生物质、分子材料等方面的应用及研究进展,并对该领域的前景进行了展望。Metal-complexed rotaxanes and catenanes are synthesized by introducing metal ions or metal complexes into rotaxanes and catenanes. They have attracted extensive attentions of chemists due to their special structures and properties. In this paper, the research progress in metal-complexed rotaxanes and catenanes used as molecular machines, molecular switches, artifical biologic meterials, molecular materials etc. is reviewed and the potential development of the research in this field is prospected.

关 键 词：金属轮烷 金属索烃 分子机器 

分 类 号：O621.2[理学—有机化学]