六(乙氧基吡咯烷酮)三聚磷腈的合成与表征  

Synthesis and Characterization of Hexakis [2-(2-oxo-1-pyrrolidinyl)Cyclotriphosphazene]

作　　者：殷跃凡[1] 黄荣[2] 李艳梅[1] 毕韵梅[1] 

机构地区：[1]云南师范大学化学化工学院,昆明650092 [2]云南大学化学科学与工程学院,昆明650031

出　　处：《化学通报》2007年第7期552-554,共3页Chemistry

基　　金：国家自然科学基金(20364002);中国科学院"西部之光"人才培养计划资助项目

摘　　要：以N-羟乙基吡咯烷酮与氢化钠作用生成相应的钠盐,再将此钠盐与六氯三聚磷腈(HCCP)发生亲核取代反应,合成了六(乙氧基吡咯烷酮)三聚磷腈,用IR、31P NMR、1H NMR、13C NMR、DEPT、FABMS等现代谱学技术对其结构进行了表征。生物活性试验表明,此化合物1mg/mL时对腐生线虫Panagrellus redivivus的72h致死率为52·7%。Synthesis, characterization and biological activity of hexakis [2-（2-oxo-1-pyrrolidinyl） cyclotriphosphazene] were described in this paper. The title compound was prepared by nucleophilic substitution reaction of hexachlorocyclotriphosphazene with sodium 1-（2-hydroxyethyl）-2-pyrrolidone which was obtained by the reaction of 1-（2-hydro- xyethyl）-2-pyrrolidone with sodium hydride. The results showed that the compound was able to kill 52. 7% of the Panagrellus redivivus at 1mg/mL within 72 hours.

关 键 词：六(乙氧基吡咯烷酮)三聚磷腈 N-羟乙基吡咯烷酮 合成 

分 类 号：O634.51[理学—高分子化学]