5,10,15,20-四(对-十四酰亚胺基苯基)卟啉及其锰、锌配合物的合成及性质  

Preparation and Properties of 5,10,15,20-Tetra(4-myristylimidophenyl) Porphyrin and Its Zn and Mn Complexes

作　　者：孙二军[1] 王栋[1] 程秀利[1] 师宇华[1] 师同顺[1] 

机构地区：[1]吉林大学化学学院,长春130012

出　　处：《高等学校化学学报》2007年第7期1208-1213,共6页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:59783001)资助

摘　　要：合成了5,10,15,20-四(对-十四酰亚胺基苯基)卟啉配体(TMPPH2)及其锰、锌金属配合物(TMPPMnCl,TMPPZn),并通过紫外-可见光谱、红外光谱、核磁共振氢谱、元素分析等技术对化合物的结构加以确认,研究了配体和配合物的拉曼光谱、光电子能谱和荧光光谱的变化及电化学性质.结果表明,配体和配合物的紫外光谱、红外光谱、拉曼光谱、荧光光谱及光电子能谱都有很大区别,锰配合物的循环伏安曲线与配体和锌配合物不同,除了卟啉环发生氧化还原外,还发生了金属离子的氧化还原反应.A new porphyrin 5,10,15,20-tetra （4-myristylimidophenyl） porphyrin （ TMPPHz ） and its complexes TMPPMnC1 and TMPPZn were synthesized and their structures were confirmed by means of elemental analyses, UV-Vis spectra, infrared spectra and 1H NMR spectra. Raman spectra, fluorescence spectra and X-ray photoelectron spectroscopy spectra of the porphyrin and its complexes were investigated. The electrochemistry of the ligand and the complexes was als0 studied. The results show that there are much difference between the ligand and the complexes in the UV-Vis spectra, infrared spectra, Raman spectra, fluorescence spectra and XPS spectra. The cyclic voltammetry of TMPPMnC1 is different from those of the ligand and TMPPZn, which showed not only the redox of the porphyrin ring, but also the redox of the metal ion Mn^3＋.

关 键 词：卟啉 配合物 拉曼光谱 荧光光谱 电化学 光电子能谱 

分 类 号：O611.4[理学—无机化学]