Novel synthesis metal 3-alkylthiophene copolymer  

新型合成金属3-烷基噻吩共聚物(英文)

作　　者：祁争健[1] 冯卫东[1] 孙岳明[1] 颜大志[1] 肖英勃[1] 何艳芳[1] 虞婧[1] 

机构地区：[1]东南大学化学化工学院,南京210096

出　　处：《Journal of Southeast University(English Edition)》2007年第2期298-301,共4页东南大学学报（英文版）

基　　金：The PhD Programs Foundation of Ministry of Edu-cation of China(No20030286012)

摘　　要：Copolymer, regiorandom and regioregular poly （ 3-octylthiophene ）-co-poly （ 3-（ 2-ethyl-1- hexylthiophene））（P3OTIOT） was synthesized by a FeCl3-oxidation and GRIM （grignard method） approach. The structure and optical properties were verified by the Fourier transform infrared, ultraviolet visible spectroscopy, NMR （nuclear magnetic resonance ）, gel permeation chromatography （GPC） and photoluminescence （PL）. The results indicate that the band-gap energy of the regioregular HT P3OTEHT was lower than that of the regiorandom copolymer and both of them depict low band-gap energy, high photoluminescence quantum yield, excellent solubility and processability, and might be promising polymer materials for applications in polymer light-emitting diodes, light-emitting electrochemical cells and polymer solar cells, etc.用FeCl3氧化聚合法和GRIM置换法合成了无规和规整的3-辛基噻吩共3-(2-乙基-1-己基)噻吩共聚物.通过红外、紫外、核磁共振、凝胶色谱和荧光光谱法对其结构和性能进行了分析与表征.结果表明:头-尾相连的规整3-辛基噻吩共3-(2-乙基-1-己基)噻吩共聚物,带隙能较无规共聚物低,且2种共聚物均表现出能垒低、荧光量子效率高、溶解性好和易于加工处理的特点,可以是一类应用于发光二极管、电化学电池和太阳能电池等领域具有广泛前景的聚合物.

关 键 词：3-alkylthiophene COPOLYMER synthesis metal 

分 类 号：O658[理学—分析化学]