One-Pot Synthesis of 1,2,3-Triazoles using Polymer-Supported Propyne in Aqueous Solution  

One-Pot Synthesis of 1,2,3-Triazoles using Polymer-Supported Propyne in Aqueous Solution

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作  者:商永嘉 任连兵 王冬梅 

机构地区:[1]College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China [2]Anhui Key Laboratory of Functional Molecular Solids, Wuhu, Anhui 241000, China

出  处:《Chinese Journal of Chemistry》2007年第8期1202-1206,共5页中国化学(英文版)

摘  要:A practical and efficient liquid-phase synthesis of 1,2,3-triazoles using poly(ethylene glycol) as support in aqueous solution was described. The title compounds, 1,2,3-triazoles 5 were obtained by a one-pot three-component 1,3-dipolar cycloaddition reaction in middle yields. In addition, a series of unexpected products 7 of Sonogashira reaction were also formed under the same condition.A practical and efficient liquid-phase synthesis of 1,2,3-triazoles using poly(ethylene glycol) as support in aqueous solution was described. The title compounds, 1,2,3-triazoles 5 were obtained by a one-pot three-component 1,3-dipolar cycloaddition reaction in middle yields. In addition, a series of unexpected products 7 of Sonogashira reaction were also formed under the same condition.

关 键 词:1 2 3-TRIAZOLE poly(ethylene glycol) 1 3-dipolar cycloaddition Sonogashira reaction 

分 类 号:O626.26[理学—有机化学]

 

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