有机无机杂化磷酸镍材料的水热合成与表征  

Synthesis and Characterization of Organic-inorganic Hybrid Material of Nickel Phosphate

作　　者：王秀丽[1] 张义建[1] 盛国定[1] 

机构地区：[1]杭州师范大学材料与化学化工学院,浙江杭州310036

出　　处：《杭州师范学院学报（自然科学版）》2007年第4期275-278,共4页Journal of Hangzhou Teachers College(Natural Science)

基　　金：浙江省自然科学基金项目(Y406341);浙江省教育厅计划项目(0686XT60);杭州师范学院自然科学重点项目(2006XNZ04)

摘　　要：在水热条件下,通过引入2,2-’bipy合成了一种有机无机杂化磷酸镍材料,通过EDX初步确定了成分,对其进行了红外光谱及XRD粉末衍射结构表征,用SEM观察了它的形貌,采用固体漫反射方法测定了吸收光谱,并用单晶衍射法初步得出了晶体的单胞参数.In hydrothermal synthetic conditions, an organic-inorganic hybrid material of nickel phosphate was synthesized. Its compositions was conformed by EDX. It was characterized by IR, XRD, SEM and UV-Vis. The IR spectrum of the compound showed the presence of vibrational bands characteristic of phosphate groups at 800- 1 200 cm^-1, and the intense band at 496 cm%-1 was attributed to the stretching vibrations of Ni--N bonds.

关 键 词：水热合成 有机无机杂化 磷酸镍 表征 

分 类 号：O614.81[理学—无机化学]