吡咯在一些聚合物基质中聚合生成导电高分子复合物的研究  

Electrically Conductive Composites Prepares By Electrochemical Polymerization of Pyrrole in Some Polymer Matrixes

作　　者：毕先同[1] 裴启兵[1] 韩宝珍[1] 宝净生[1] 

机构地区：[1]中国科学院化学研究所

出　　处：《功能高分子学报》1990年第2期113-121,共9页Journal of Functional Polymers

摘　　要：用电化学氧化聚合方法将吡咯在聚氨酯(PU)、聚已内酰胺(Nylon 6)、聚芳砜酰胺(PSu)及聚对苯二甲酰对苯二胺(PPTA)等绝缘聚合物中聚合生成聚吡咯(PP_y)的高分子复合物PU/PP_y、Nylon 6/PP_y、PS_u/PP_y、PPTA/PP_y等。它们具有良好的电导率及力学性能、报导了他们的制备方法及电导率、力学性能、电化学活性、扫描电镜、X-射线衍射的表征。In this Paper, the improvement of the mechanical properties of polypyrrole (PPy) by electrochemical preparation of conductive composite film from pyrrole (Py) and non-conductive polymers are presented. Nylon-6, Poly(p-phenyleneterephthalamide) (PPTA), polysulfone (PSu) and polyurethane (PU) are used as the non-conductive poymers, Py and dopants can penetrate through a polymer substrate (precoated on a Pt electrode by casting) and electropolymerized firet on the pt surface, then polymerized in the nonconductive Polymer matrix. The prepration, electrical conductivity, mechamical propert SEM and CV curve of the composites are all reported.

关 键 词：聚吡咯 导电复合物 聚合物基质 

分 类 号：TM243[一般工业技术—材料科学与工程]