催化酯化合成丁酸正丁酯的研究进展  

Research Progress on Synthesis of n-butyl Butyrate by Catalytic Esterification

作　　者：刘美艳[1] 俞善信[1] 管仕斌[1] 

机构地区：[1]湖南师范大学化学化工学院,湖南长沙410081

出　　处：《化工中间体》2007年第8期18-23,共6页

摘　　要：固体催化剂代替硫酸作为酯化的催化剂,评述了对甲苯磺酸、甲烷磺酸盐、氨基磺酸、强酸性阳离子交换树脂、三氯化铁、二氯化锡、四氯化锡、硫酸铁铵、硫酸亚铁,硫酸铈、硫酸钛、硫酸氢钠、季铵盐、固体超强酸、杂多酸、分子筛等固体催化剂和酶催化酯化合成丁酸正丁酯的方法。Solid catalyst can be used as catalyst for the esterification instead of sulphuric acid. The catalytic synthesis of n-butyl butyrate with p-toluene sulfonic acid. methane sulfonate, amino sulfonic acid, strongly acidic cationic exchange resin, ferric chloride, stannous chloride, stannic chloride, am- monium ferric sulfate, ferrous sulfate, cerium sulfate, titanium sulfate, sodium bisulfate, quaternary ammonium salt, solid supper acid, heteropoly acid, and molecular sieve et al solid catalyst and enzyme catalysis esterification were reviewed.

关 键 词：丁酸正丁酯 合成 固体催化剂 催化酯化 

分 类 号：O623.624[理学—有机化学] TQ225.24[理学—化学]