新型微孔钨磷多金属氧酸盐(C_2N_2H_(10))_2[H_2P_2W_(18)O_(62)]·8H_2O的水热合成和电化学性质  

A novel tungsten polyoxometalate(C_2N_2H_(10))_2[H_2P_2W_(18)O_(62)]·8H_2O with a microporous structure: synthesis and electrochemical behavior

作　　者：刘宗瑞[1] 崔毅[1] 段丽梅[1] 徐秀廷[1] 董哲[1] 

机构地区：[1]内蒙古民族大学化学学院,内蒙古通辽028043

出　　处：《分子科学学报》2007年第4期276-280,共5页Journal of Molecular Science

基　　金：内蒙古自然科学基金资助项目(20001301);内蒙古自治区人才开发基金资助项目(20061012)

摘　　要：采用水热法并以乙二胺为模板剂合成了具有微孔结构的钨磷多金属氧酸盐(C2N2H10)2[H2P2W18O62].8H2O.通过元素分析、等离子发射光谱、X射线单晶衍射等进行了结构表征,并用电化学方法对标题化合物的电化学性质进行了研究.A microporous tungsten polyoxometalate, （C2N2H10）2[H2P2W18O62]·8H2O has been synthesized hydrothermally with ethylenediamine as the structure-directing agent,and the title compound has been characterized by elemental analysis and single-crystal X-ray structure analysis. The electrochemistry property of the compound has been investigated by electrochemistry method.

关 键 词：水热合成 晶体结构 多金属氧酸盐 电化学性质 

分 类 号：O612[理学—无机化学]