配合物[Ag(chlsp)_2](F_3CCOO)的合成,谱学和晶体结构(英文)  

Synthesis,Spectra and Crystal Structure of Complex [Ag(chlsp)_2](CF_3CO_2)

作　　者：高洪苓[1] 林通[1] 亢惠娟[1] 陈雄斌[1] 

机构地区：[1]天津大学化学系,天津300072

出　　处：《无机化学学报》2007年第8期1429-1431,共3页Chinese Journal of Inorganic Chemistry

基　　金：天津大学青年教师基金资助项目(No.5110124,5110111)。

摘　　要：A silver(I) complex [Ag(chlsp)2](CF3CO2),(chlsp=(E)-4-(4-chlorostyryl) pyridine),was synthesized by the reaction between AgCF3CO2 and chlsp in the anhydrous enthnol. The crystal structure of [Ag(chlsp)2](CF3CO2) was characterized by elemental analysis,IR and determined by using single crystal X-ray diffraction. The result shows that the complex crystallize in triclinic system,with space group P1,a=0.109 7(2) nm,b=0.111 7(2) nm,c=0.117 2(2) nm,α=73.60(3)°,β=85.03(3)°,γ=81.82(3)°,V=0.136 2(4) nm3,Z=2. The moleculars are connected by Ag…Ag and Ag…Cl interactions,resulting in a three-dimensional network.A silver（I） complex [Ag（chlsp）2]（CF3CO2）,（chlsp=（E）-4-（4-chlorostyryl） pyridine）,was synthesized by the reaction between AgCF3CO2 and chlsp in the anhydrous enthnol. The crystal structure of [Ag（chlsp）2]（CF3CO2） was characterized by elemental analysis,IR and determined by using single crystal X-ray diffraction. The result shows that the complex crystallize in triclinic system,with space group P1,a=0.109 7（2） nm,b=0.111 7（2） nm,c=0.117 2（2） nm,α=73.60（3）°,β=85.03（3）°,γ=81.82（3）°,V=0.136 2（4） nm^3,Z=2. The moleculars are connected by Ag…Ag and Ag…Cl interactions,resulting in a three-dimensional network. CCDC： 631131.

关 键 词：反-4-(4-氯苯乙烯基)吡啶 银配合物 晶体结构 三维网络 

分 类 号：O614.122[理学—无机化学]