线型氯甲基聚苯乙烯的制备新方法  

New Method of Preparing Linear Chloromethylated Polystyrene

作　　者：申艳玲[1] 高保娇[1] 

机构地区：[1]中北大学化学工程系,山西太原030051

出　　处：《合成化学》2007年第4期426-429,共4页Chinese Journal of Synthetic Chemistry

基　　金：山西省自然科学基金资助项目(20040402JJ)

摘　　要：在均相反应体系中,以SnCl4为催化剂,CCl4为溶剂,自制的1,4-二氯甲氧基丁烷(BCMB)为氯甲基化试剂,制得了完全线型化的氯甲基聚苯乙烯(CMPS),其结构和组成经IR和佛尔哈德分析法表征。最佳氯甲基化反应条件为:聚苯乙烯2.0 g,BCMB 10 mL,SnCl41 mL,CCl430 mL,于18℃反应17 h。在最佳反应条件下,CMPS的氯甲基化程度达68%。The chloromethylation of polystyrene（PS） was performed greenly in a homogeneous system by using self-made 1,4-his（ chloromethoxy）butane as the chloromethylation reagent, SnCl2 and CCl4 as the catalyst and solvent. The chloromethylated polystyrene（CMPS） with 68% of chloromethylation degree and complete linearity was obtained. The chemical structure and composition of CMPS were characterized by IR and Volhard method. The optimum reaction conditions at 18℃ for 17 h were as follows： PS was 2.0 g; BCMB was 10 mL; SnCl4 was 1 mL; CCl4 was 30 mL.

关 键 词：聚苯乙烯 1 4-二氯甲氧基丁烷 氯甲基化反应 

分 类 号：O632.13[理学—高分子化学]