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作 者:ZHANG Zheng-Jie MA Dong-Ping
机构地区:[1]College of Information Engineering, Chengdu University of Technology, Chengdu 610059, China [2]Department of Applied Physics, Sichuan University, Chengdu 610065, China
出 处:《Communications in Theoretical Physics》2007年第2X期357-362,共6页理论物理通讯(英文版)
摘 要:By means of improved ligand-field theory, the "pure electronic" pressure-induced shift (PS) and the PS due to electron-phonon interaction (EPI) of R-line of MgO:Cr^3+ have been calculated, respectively. The calculated results are in very good agreement with the experimental data. The behaviors of the pure electronic PS of R-line of MgO:Cr^3+ and the PS of its R-line due to EPI are different. It is the combined effect of them that gives rise to the total PS of R-line, which has satisfactorily explained the experimental results. The comparison between the feature of R-line PS of MgO:Cr^3+ and that of R1-line PS of ruby has been made.
关 键 词:high-pressure effect electron-phonon interaction R-line improved ligand-field theory admixture of |t2^2(3T1)e^4T2) and |t2^32E)
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