亚甲基[6,6]-Fullerene[C_(60)]单羧酸衍生物的合成  

Synthesis of Methylene[6,6] Fullerene Carboxylic Acid Derivatives

作　　者：叶光明[1] 倪瑾[2] 姜云云[3] 吴秋业[3] 廖洪利[3] 

机构地区：[1]解放军第101医院,江苏无锡214044 [2]第二军医大学放射医学研究所,上海200433 [3]第二军医大学药学院有机教研室,上海200433

出　　处：《精细化工中间体》2007年第4期29-31,共3页Fine Chemical Intermediates

基　　金：国家自然基金资助项目(30200069)。

摘　　要：以溴乙酸乙酯、硫醚和Fullerene[60]为原料合成Fullerene[60]羧酸乙酯,再经水解、酸化得到亚甲基[6,6]-Fullerene[C60]单羧酸,并进一步反应得其酰胺。这些新化合物的结构经IR和1HNMR确证。Methylene [ 6,6 ] fullerene carboxylic acid was synthesized through hydrolysis and acidification of fullerene carboxylic ester which was prepared from bromoacetate ethyl, dimethyl sulfide and fullerene [60] . Methylene [6,6 ] fullerene carboxylic acid was further used to synthesize amide. The structures of the new compounds were characterized by IR and 1H NMR.

关 键 词：富勒烯 硫叶立德 单羧酸 

分 类 号：O635.1[理学—高分子化学]