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机构地区:[1]中南民族大学化学与材料科学学院催化材料科学湖北省重点实验室,武汉430074 [2]武汉大学化学与分子科学学院,武汉430072
出 处:《化学进展》2007年第9期1381-1392,共12页Progress in Chemistry
基 金:国家自然科学基金项目(No.20474044)资助
摘 要:本文总结了近年来荧光聚合物的研究进展,主要介绍了荧光聚合物的分类:按其溶解性能可分为非水溶性、水溶性和两亲荧光聚合物3大类;荧光聚合物的合成:荧光化合物为引发剂、荧光化合物为链转移剂、荧光功能单体聚合、荧光化合物与聚合物的化学键合、非荧光功能单体聚合等5种制备荧光聚合物的设计合成方法;荧光聚合物的应用:荧光聚合物在荧光化学传感器、荧光分子温度计、荧光造影、药物载体、荧光探针等方面的应用研究。During the past two decades, research on fluorescent polymers has attracted increasing interests because of their important application in the fields of life science and medicine. The latest research progress in fluorescent polymers is summarized as follows. ( 1 ) Classification of fluorescent polymers. Although there are different methods to classify fluorescent polymers, according to its solubility, fluorescent polymers can be divided into three types which is hydrophobic, hydrophilic and amphiphilic, individually; (2) Five methods of design and synthesis of fluorescent polymers. Fluorescent polymers can be synthesized by using fluorescent compounds as initiator, fluorescent compounds as chain transfer agents, polymerization of fluorescent functional monomers, chemical bonding between fluorescent compounds and polymers, polymerization of non-fluorescent functional monomer. (3) Applications of fluorescent polymers. Fluorescent polymers are functional macromolecules with important application prospect. Their applications in the fields of fluorescent chemosensor, fluorescent molecular thermometers, fluorescent imaging, drug delivery carriers and fluorescent probe are briefly introduced in this paper.
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