疏水改性丙烯酰胺共聚物在水溶液中的缔合  

Association of Hydrophobically Acrylamide-Modified Copolymer in Aqueous Solution

作　　者：钟传蓉[1] 黄荣华[2] 代华[2] 

机构地区：[1]西南石油大学油气藏地质及开发工程国家重点实验室,四川成都610500 [2]高分子材料工程国家重点实验室四川大学高分子研究所,四川成都610065

出　　处：《高分子材料科学与工程》2007年第5期88-91,共4页Polymer Materials Science & Engineering

基　　金：国家重点基础研究发展规划"973"资助项目(G1999022502)

摘　　要：罗丹明B荧光探针发现丙烯酰胺(AM)/丁基苯乙烯(BST)/2-甲基-2-丙烯酰胺基丙磺酸钠(NaAMPS)共聚物(PASA)在0.05 g/dL水溶液中疏水微区的黏度已较大,说明PASA具有强的疏水缔合效应。动态光散射结果表明,PASA在0.005 g/dL极稀溶液中,主要以单分子存在,部分单分子链发生了分子内缔合;在0.01 g/dL^0.2 g/dL范围内,溶液中均有构象伸展和卷曲的单分子存在,粒径有单分子区和疏水缔合区;当共聚物浓度增加为0.3 g/dL时,流体力学半径分布为单分散,只有缔合体存在。随着分子中疏水链段含量的增加,0.1 g/dL PASA溶液的疏水缔合体(Rh:2800 nm^5000 nm)的数量增加,溶液黏度显著升高。The viscosity measurement of the poly （acrylamide/butylstyrene/sodium 2-acrylamido-2-methylpropane sulphonate） （PASA） in microenvironment using rhodamin B as the fluorescent probe shows that the microviscosity of 0. 05 g/dL PASA solution is very high, indicating strong intermoleeular association of hydrophobic groups. The studies of dynamic light scattering show that the polymer molecules mainly exist in the form of mono-molecule and intramolecular associations occuring in the 0. 005 g/dL PASA aqueous solution. In 0.01 g/dL-0. 2 g/dL PASA aqueous solution, the hydrodynamic radius （Rh） distribution consists of two regions, expanding and coiled mono-molecules, and hydrophobic associating molecules. The distribution of Rh in 0.3 g/dL PASA aqueous solution is mono-disperse, and only aggregates exist. With increasing hydrophobic monomer content in the polymer molecules, the number of aggregates with RhOf 2800 nm^5000 nm increases in 0.1 g/dL PASA aqueous solution, resulting in the remarkable increase in the apparent viscosity of PASA aqueous solution.

关 键 词：丁基苯乙烯 微环境黏度 动态光散射 

分 类 号：TQ326.4[化学工程—合成树脂塑料工业]