酞菁钴及其衍生物对Li/SOCl_2电池性能的影响  

The effects of cobalt phthalocyanine and its derivatives on the performance of Li/SOCl_2 cell

作　　者：许占位[1] 宋艳虹[1] 车兔林[1] 赵建社[1] 

机构地区：[1]西北大学化学系,陕西西安710069

出　　处：《电池》2007年第4期297-299,共3页Battery Bimonthly

基　　金：国家自然科学基金(No.20671076)资助

摘　　要：通过恒电阻放电实验研究了酞菁钴[Co(Ⅱ)Pc]及其衍生物[Co(Ⅱ)TcaPc、Co(Ⅱ)TcPc、Co(Ⅱ)TeaPc、Co(Ⅱ)OcPc和Co(Ⅱ)CcPc]对Li/SOCl2电池性能的影响;分析了不同类型取代基及其数量的酞菁钴配合物对Li/SOCl2电池的催化作用、对放电电压和放电时间的影响,结果表明:Co(Ⅱ)CcPc共催化剂有较好的催化活性。Effects of cobalt phthalocyanine [Co（ Ⅱ）Pc] and its derivatives [Co（ Ⅱ ） TcaPc, Co（ Ⅱ ） TcPc, Co（ Ⅱ） TeaPc, Co （Ⅱ）OcPc and Co（Ⅱ ）CcPc] on the performance of Li/SOCl2 cell were studied by the constant resistance discharge test. The catalytic action of the cobalt phthalocyanine coordination compound with different types and amounts of substituent groups on the Li/SOCl2 cell, their effects on the discharge voltage and time were analyzed. The results showed Co（Ⅱ）CcPc as co-catalyst, had good catalytic activity.

关 键 词：酞菁钴 LI/SOCL2电池 催化剂 

分 类 号：TM911.1[电气工程—电力电子与电力传动]