水相悬浮法氯化高全同聚丁烯-1性能的研究  

Property of Chlorinated High Isotactic Polybutene-1 Using Aqueous Suspension Method

作　　者：周婷婷[1] 赵永仙[1] 姚薇[1] 邵华峰[1] 黄宝琛[1] 

机构地区：[1]青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛266042

出　　处：《现代塑料加工应用》2007年第4期23-26,共4页Modern Plastics Processing and Applications

基　　金：国家863基金(2006AA03z546)赞助

摘　　要：采用水相悬浮法氯化高全同聚丁烯-1(HIPB-1),其氯化产物氯化高全同聚丁烯-1(CHIPB-1)通过差示扫描量热法进行测试和分析。结果表明:HIPB-1被氯化后仍存有HIPB-1的晶型特征,随着氯含量增加,CHIPB-1的溶解性变好,CHIPB-1的特性粘数减小;氯质量分数在30%～60%时,CHIPB-1的热降解温度缓慢升高,氯质量分数超过60%时,其热降解温度明显上升;CHIPB-1的密度、拉伸强度及硬度要比HIPB-1的高,但是其断裂伸长率和维卡软化温度明显下降。High isotactic polybutene-1 （HIPB-1） was chlorinated by aqueous suspension method. Chlorination products CHIPB-1 were tested and analyzed through DSC. The results show that CHIPB-1 still contains crystallization characteristic of HIPB-1. With increasing the chlorine content, solubility of CHIPB-1 becomes good, intrinsic viscosity number of CHIPB-1 reduces. When chlorine content is between 30% and 60%, heat-degradation temperature of CHIPB-1 rises slowly. When chlorine content exceeds 60%, heat-degradation temperature of CHIPB-1 rises quickly. The tensile strength, hardness and density of CHIPB-1 are higher than those of HIPB-1, but enlongation at break and Vicat softening point bring down obviously.

关 键 词：氯化高全同聚丁烯-1 溶解性能 物理性能 热解温度 

分 类 号：TQ325.12[化学工程—合成树脂塑料工业]