出 处:《岩石学报》2007年第1期117-124,共8页Acta Petrologica Sinica
基 金:financial support from National Natural Science Foundation of China (49972031 and and 40572066).
摘 要:Mantle xenoliths are common in the Cenozoic basalts of the Changbaishan District,Jilin Province,China.Sulfide assemblages in mantle minerals can be divided into three types:isolated sulfide grains,sulfide-meh inclusions and filling sulfides in fractures.Sulfide-meh inclusions occur as single-phase sulfides,sulfide-silicate melt,and CO_2-sulfide-silicate melt inclusions. Isolated sulfide grains are mainly composed of pyrrhotite,but cubanite was found occasionally.Sulfide-meh inclusions are mainly composed of pontlandite and MSS,with small amounts of chalcopyrite and talnakhite.The calculated distribution coefficient K_(D3)for lherzolite are similar to that of mean experimental value.The bulk sulfides in lherzolite were in equilibrium with the enclosing minerals, indicating immiscible sulfide melts captured in partial melting of upper mantle.Sulfide in fractures has higher Ni/Fe and(Fe+Ni)/S than those of sulfide melt inclusions.They might represent later metasomatizing fluids in the mantle.Ni/Fe and(Fe+Ni)/S increase from isolated grains,sulfide inclusions to sulfides in fractures.These changes were not only affected by temperature and pressure,hut by geochemistry of Ni,Fe and Cu,and sulfur fugacity as well.Mantle xenoliths are common in the Cenozoic basalts of the Changbaishan District, Jilin Province, China. Sulfide assemblages in mantle minerals can be divided into three types: isolated sulfide grains, sulfide-meh inclusions and filling sulfides in fractures. Sulfide-inch inclusions occur as single-phase sulfides, sulfide-silicate melt, and CO2-sulfide-silicate melt inclusions. Isolated sulfide grains are mainly composed of pyrrhotite, but cubanite was found occasionally. Sulfide-inch inclusions are mainly composed of pentlandite and MSS, with small amounts of chalcopyrite and talnakhite. The calculated distribution coefficient KD3 for lherzolite are similar to that of mean experimental value. The bulk sulfides in lherzolite were in equilibrium with the enclosing minerals, indicating immiscible sulfide melts captured in partial melting of upper mantle. Sulfide in fractures has higher Ni/Fe and (Fe + Ni)/S than those of sulfide melt inclusions. They might represent later metasomatizing fluids in the mantle. Ni/Fe and ( Fe + Ni )/S increase from isolated grains, sulfide inclusions to sulfides in fractures. These changes were not only affected by temperature and pressure, but by geochemistry of Ni, Fe and Cu, and sulfur fugacity as well.
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