生物标志化合物立体异构重排的微观物理解释  

A Microphysical Interpretation for Stereoisomer Rearrangement of Biomarker Compound

作　　者：周炎如[1] 

机构地区：[1]中国石油石油勘探开发科学研究院西北分院,兰州730020

出　　处：《新疆石油地质》2007年第5期523-528,共6页Xinjiang Petroleum Geology

摘　　要：应用微观粒子波动和分子轨道理论,解释生物标志化合物在沉积体系中自身独有的"电子离域-外质子磁旋反应"的重排机理。首先阐明生物标志化合物立体异构重排的理论依据;然后分别探讨了萜、甾烷类立体异构重排和成熟度对应关系;极性、非极性生物标志化合物异构体重排和油气运移对应关系。In this paper, the stereoisomer rearrangement of biomarker compound for the exclusive reaction form the electronic off-domain to the out-proton magnetic rotation is interpreted in the sedimentary system in terms of the micro-particle wave motion and the molecular orbital theory. First of all, the theoretic basis for the stereoisomer rearrangement of biomarker compound is illustrated, and then the corresponding relations between the sterane/terpane stereoisomer rearrangement and maturity, as well as the polarity/non-polarity and petroleum migration are discussed, respectively.

关 键 词：生物标志物 异构体 粒子 分子 

分 类 号：TE112.1[石油与天然气工程—油气勘探]