螺恶嗪化合物在有机溶液中的酸致变色研究  

The acidichromism of spirooxazine compound in the organic solvent

作　　者：杨志范[1] 李泽[1] 程伟[1] 刘晓运[1] 

机构地区：[1]长春工业大学化学工程学院,吉林长春130012

出　　处：《长春工业大学学报》2007年第3期333-336,共4页Journal of Changchun University of Technology

基　　金：吉林省科技厅基础理论资助项目(20010513)

摘　　要：合成了四种螺恶嗪光致变色化合物,并对它们在有机溶剂中所表现的酸致变色现象进行了研究。发现它们与盐酸在室温下形成的复合物(SP.HCl),随溶液极性的增加,其吸光强度增大,吸收光谱发生蓝移。Four kind of spironaphthooxazine compounds are synthesized, and the acidichromism phenomenon in the acidic organic solvent is studied. It is discovered that the light absorption density of the compound SP · HCl （four spironaphthooxazine compounds and hydrochloric acid）, under the room temperature, will increase with the solution polar, and the absorption spectrum has the blue shift.

关 键 词：酸致变色 光致变色 螺恶嗪 蓝移 

分 类 号：O621.3[理学—有机化学]