酞菁配合物对锂-亚硫酰氯电池正极的催化作用  

Studies on Catalytic Mechanism of Li/SOCl_2 Batteries by Metal Phthalocyanine Complexes

作　　者：许占位[1] 孙庆津[1] 苏碧云[1] 车兔林[1] 宋艳虹[1] 李要民[2] 赵建社[1] 

机构地区：[1]西北大学化学系陕西省物理无机化学重点实验室,陕西西安710069 [2]西安机电信息研究所,陕西西安710065

出　　处：《电化学》2007年第3期293-296,共4页Journal of Electrochemistry

基　　金：国家自然科学基金(No.20671076)资助

摘　　要：合成过渡金属酞菁配合物MPc(M=Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),N i(Ⅱ),Cu(Ⅱ)),研究MPc及其中心离子对L i/SOC l2电池正极的催化作用,并提出相关催化机理.Effects of metal phthalocyanine comlexes MPc （ M = Mn （ Ⅱ）, Fe （ Ⅱ ）, Co （ Ⅱ ）, Ni （ Ⅱ ）, Cu （ Ⅱ ） ） as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance. And the reasons of MPc affecting the discharged voltage and discharged also brought forward. A few new viewpoints on the catalytic mechanism of the phthalocyanine complexes were proposed time of Li/SOCl2 batteries were reduction of thionyl chloride by

关 键 词：过渡金属 酞菁配合物 锂/亚硫酰氯(Li/SOCl2) 催化机理 

分 类 号：TM912[电气工程—电力电子与电力传动]