The First Homochiral Diamond-Like Coordination Polymer Containing Cubane Cluster （Cu4I4） as Connecting Node and Cinchonine as Donor-Acceptor （or Push-Pull Electronic Effect） Building Block  

作　　者：王国喜 熊仁根 

机构地区：[1]Coordination Chemistry Institute, Nanjing University, Nanjing, Jiangsu 210093, China [2]Ordered Matter Science Research Center, Southeast University, Nanjing, Jiangsu 211189, China

出　　处：《Chinese Journal of Chemistry》2007年第10期1405-1408,共4页中国化学（英文版）

基　　金：Project supported by 973 project （No. 2025103）, the National Natural Science Foundation of China （No. 2003028400） and the Distinguished Young Scholar Fund from the National Natural Science Foundation of China （No. 2006CB806104）.

摘　　要：The reaction of CuI with cinchonine （an organic donor-acceptor chromophore） afforded a homochiral 3D diamondoid network [Cu4I4（cinchonine）2]n （1） containing a cubane cluster （Cu4I4） as a connecting node. This is the first homochiral coordination polymer with diamondoid nets containing a cluster as a connecting note. Its thermal stability and solid state optical properties such as fluorescence, circular dichroism and second-harmonic generation response were also reported.The reaction of CuI with cinchonine （an organic donor-acceptor chromophore） afforded a homochiral 3D diamondoid network [Cu4I4（cinchonine）2]n （1） containing a cubane cluster （Cu4I4） as a connecting node. This is the first homochiral coordination polymer with diamondoid nets containing a cluster as a connecting note. Its thermal stability and solid state optical properties such as fluorescence, circular dichroism and second-harmonic generation response were also reported.

关 键 词：CINCHONINE CuI DIAMOND-LIKE CUBANE second-harmonic generation 

分 类 号：O641.4[理学—物理化学]