含四硫富瓦烯大环化合物的合成与研究进展  

Advances in Synthesis and Research of Macrocyclic Compounds Containing Tetrathiafulvalene

作　　者：李洪启[1] 宋燕西[2] 彭家建[3] 邱化玉[3] 

机构地区：[1]东华大学化学与化工学院,上海201620 [2]东华大学环境科学与工程学院,上海201620 [3]杭州师范学院有机硅化学及材料技术重点实验室,杭州310012

出　　处：《有机化学》2007年第10期1220-1227,共8页Chinese Journal of Organic Chemistry

基　　金：教育部留学回国人员科研启动基金;上海市自然科学基金(No.06ZR14001)资助项目

摘　　要：简要介绍了含有四硫富瓦烯(TTF)单元的大环化合物的分类,概括了各类含四硫富瓦烯大环化合物的合成方法,主要包括含有1,3-二硫杂环戊烯-2-硫酮单元的大环化合物在亚磷酸三烷基酯参与下的偶合反应,以及带有氰乙基硫等取代基的预先合成的官能化TTF与二卤代低聚醚的反应.综述了含四硫富瓦烯大环化合物的电化学性能及其在分子识别方面应用研究的最新进展,提出了含四硫富瓦烯大环化合物的发展趋势.Classification of macrocyclic compounds containing tetrathiafulvalene is introduced briefly. The synthetic methods of macrocyclic compounds containing tetrathiafulvalene are outlined, which mainly include the coupling reaction of a macrocyclic compound containing a 1,3-dithiole-2-thione unit mediated by trialkyl phosphite and reactions between a well-designed tetrathiafulvalene functionalized by cyanoethylthio groups or other substituents and an oligo （ethylene glycol） dihalide. The latest advances in research on electrochemical properties and applications to molecular recognition of macrocyclic compounds containing tetrathiafulvalene are reviewed. The development trends in research on such macrocyclic compounds containing tetrathiafulvalene are proposed.

关 键 词：四硫富瓦烯 大环化合物 合成 电化学性能 分子识别 

分 类 号：O624[理学—有机化学]