Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of Complex Cu(α-Furacrylic acid)_2(phen)  

作　　者：李薇 李昶红 杨颖群 匡云飞 

机构地区：[1]Department of Chemistry and Materials Science,Hengyang Normal University [2]Department of Chemical Engineering,Hunan Institute of Technology

出　　处：《Chinese Journal of Structural Chemistry》2007年第10期1228-1231,共4页结构化学（英文）

基　　金：the Foundation of Education Committee of Hunan Province (06C195);the Research Award Fund for Outstanding Young Teachers of Hengyang Normal University (2006);the Construct Program of the.Key Discipline in Hunan Province.

摘　　要：The title complex （C26H18CuN206, Mr= 517.96） has been synthesized by the reaction of α-furanacrylic acid with 1,10-phenanthroline （phen） in the solvent mixture of water and methanol. Crystal data： monoclinic, space group C2/c with a = 2.2927（4）, b = 1.01248（18）, c = 1.05061（18） nm, β = 111.188（3）°, V= 2.274（7） nm^3, Dc = 1.513 g/cm^3, Z = 4, F（000） = 1060,μ = 1.007mm^-1, R = 0.0320 and ωR = 0.0781. The crystal structural analysis shows that the copper atom is coordinated with four oxygen atoms from two α-furacrylic acids and two nitrogen atoms from 1,10-phenanthroline, giving a distorted octahedral coordination geometry. The result of electrochemical analysis shows that the electron transfer in the electrode reaction is quasi-reversible.The title complex （C26H18CuN206, Mr= 517.96） has been synthesized by the reaction of α-furanacrylic acid with 1,10-phenanthroline （phen） in the solvent mixture of water and methanol. Crystal data： monoclinic, space group C2/c with a = 2.2927（4）, b = 1.01248（18）, c = 1.05061（18） nm, β = 111.188（3）°, V= 2.274（7） nm^3, Dc = 1.513 g/cm^3, Z = 4, F（000） = 1060,μ = 1.007mm^-1, R = 0.0320 and ωR = 0.0781. The crystal structural analysis shows that the copper atom is coordinated with four oxygen atoms from two α-furacrylic acids and two nitrogen atoms from 1,10-phenanthroline, giving a distorted octahedral coordination geometry. The result of electrochemical analysis shows that the electron transfer in the electrode reaction is quasi-reversible.

关 键 词：copper（Ⅱ） complex hydrothermal synthesis electrochemical property 

分 类 号：O621[理学—有机化学]